Lots of details about metric paper sizes
\documentclass[twoside,letterpaper]{article}
\documentclass[a4paper,11pt]{report}
C.U.'s thesis class uses letterpaper by default,
but otherwise the default paper size is determined in some
configuration file (texinfo.tex?) somewhere in the TeX directory.
\documentclass[twoside,letterpaper]{article}
\documentclass[twoside,a4paper]{article}
\documentclass[letterpaper,11pt]{report}
\documentclass[a4paper,11pt]{report}
This is redundant for the C.U. Boulder
thesis class,
because letterpaper is indicated in
the thesis.cls file and a4paper is
disallowed.
You may additionally fiddle with the default margins for the indicated class and paper size (with the exception of thesis class!) by redefining length variables like \textwidth, \textheight, \topmargin, \oddsidemargin, etc.
With the explicit Unix command you can specify a paper size with the -t option, e.g.,
unix> dvips -t letter mydoc.dvi -o mydoc.ps unix> dvips -t a4 eurodoc.dvi -o eurodoc.ps unix> dvips -t legal lawdoc.dvi -o lawdoc.ps
With some LaTeX installations with a GUI (like MikTeX or TeXShop) you can either find some menu item that lets you specify a dvips paper size, or use a text editor to edit the configuration file appropriately. For MikTeX, edit (WinEdt) and save the file C:\MiKTeX\dvips\config\config.ps, moving the lines about letter and letterSize before the lines about a4 if you want letterpaper to be the default size.